You can also set the cache-size to 0, close K-Meleon, restart it and set the values to the previous ones. But it's not comfortable. I'd like to have a button "Delete the cache", too.
Combining the answer of Rab,followed by Andrew's,the location is correct,i.e
c:\windows\application data\kmeleleon\Profiles\whatever your profile is or default\blahblah.*.slt\cache. It is actually easy to find.